#The note c download#

For these substances, the risk phrases R20, R21, R22, R23, R24, R25, R26, R27, R28, R39, R68 (harmful), R48 and R65 and all combinations of these risk phrases shall be preceded by the word ‘Also’. Note E (Table 3.2): Substances with specific effects on human health (see Chapter 4 of Annex VI to Directive 67/548/EEC) that are classified as carcinogenic, mutagenic and/or toxic for reproduction in categories 1 or 2 are ascribed Note E if they are also classified as very toxic (T+), toxic (T) or harmful (Xn). In this case, the supplier must state on the label the name of the substance followed by the words ‘non-stabilised’.

However, such substances are sometimes placed on the market in a non-stabilised form.

It is in this form that they are listed in Part 3. Note D: Certain substances which are susceptible to spontaneous polymerisation or decomposition are generally placed on the market in a stabilised form. In this case the supplier must state on the label whether the substance is a specific isomer or a mixture of isomers. Note C: Some organic substances may be marketed either in a specific isomeric form or as a mixture of several isomers. Unless otherwise stated, it is assumed that the percentage concentration is calculated on a weight/weight basis.

In this case the supplier must state the percentage concentration of the solution on the label. In Part 3 entries with Note B have a general designation of the following type: ‘nitric acid … %’. Note B: Some substances (acids, bases, etc.) are placed on the market in aqueous solutions at various concentrations and, therefore, these solutions require different classification and labelling since the hazards vary at different concentrations. In this case, the supplier is required to state on the label the correct name, due account being taken of section 1.1.1.4. In Part 3, use is sometimes made of a general description such as ‘. Note A: Without prejudice to Article 17(2), the name of the substance must appear on the label in the form of one of the designations given in Part 3. The classification as a carcinogen or mutagen need not apply if it can be shown that the substance contains less than 0,1 % w/w benzene (EINECS No 200-753-7). However, if you use this classification, you might have over-classified your product without checking the content of benzene in your product first since you did not pay attention to note P. If you search the CLP annex VI table, you will know the given classification is H304 (Asp. Let's assume that you need to prepare a SDS for a very common solvent: natural gasoline ( CAS ). Please do read notes (i.e., A, B, H, L, U) for each Annex VI entry which contain conditions for the harmonized classifications to apply.Please do pay attention to specific concentration limits and M-factors.In this case, the correct classification for physical hazards shall be confirmed by testing For some entries (indicated by the reference ****), harmonized classification has not included physical hazards due to insufficient data.Classification in the more severe category must then be applied If a manufacturer or importer has access to data or other information that lead to classification in a more severe category compared to the minimum classification.For certain hazard classes, including acute toxicity and STOT repeated exposure, the classification in the Annex shall be considered as a minimum classification.

#The note c download#

You can click here to download the complete table.Īpplying harmonized classification in the Annex VI without considering the following factors is wrong!

Using harmonized classification will greatly simplify your SDSs and label preparation work. The table below is an example of several entries in the Annex VI. Example of Harmonized Classifications in Annex VI In this article, we will explain the factors to consider when using harmonized classification with a focus on the notes for the annex VI to the CLP regulation. It is mandatory for the suppliers of the respective substances or mixture to apply harmonized classification and labelling to prepare their GHS labels and safety data sheets. Explanation of the Notes for the Annex VI to CLP RegulationĪnnex VI to the CLP Regulation contains a list of harmonized classification and labelling for around 7,000 hazardous substances.